Triage under pressure. The queue does not stop because you don't know the answer. You learn to size a problem in under a minute, decide what needs ownership and what needs deflecting, and move on. Nobody teaches this on a course. You get it by doing it badly for six months and then less badly.
User translation. Turning what somebody is describing into what is actually wrong. This is a senior engineering skill. Most architects who can't do it were never on the desk.
Operational instinct. Check the obvious thing first. Suspect the recent change. Distrust the user's theory of what changed. You build this from outages. Not textbooks.
Calm under fire. The ability to stay useful when the room gets tense. Promotion panels score it heavily. People who skipped the desk often score it worst.